Marvel Platinum: The Definitive Spider-Man

At a scientific demonstration about radiation, high-school student Peter Parker is accidentally bitten by an irradiated spider, which bestows upon him the arachnid's incredible abilities. When a burglar kills his beloved Uncle Ben, the grief-stricken Peter learns a valuable lesson: that with great power there also comes great responsibility. He vows to use his new-found powers to help his fellow man and becomes the Amazing Spider-Man. This brings together the very best tales from Spidey's 50-year history. Collecting Amazing Fantasy Vol. 1 #15, Amazing Spider-Man Vol. 1 #121-122, #300, #500, #545 and #600, Amazing Spider-Man Annual #21, and Sensational Spider-Man Vol. 2 #41.